Biomass juncus derived carbon modified with Fe3O4 nanoparticles toward activating peroxymonosulfate for efficient degradation of tetracycline
Journal of Water Process Engineering(2023)
摘要
In this work, Fe3O4 nanoparticles anchored biomass juncus derived carbon (Fe3O4@JDC) was developed as a highly efficient heterogeneous peroxymonosulfate (PMS) activator to degrade organic pollutants. As-prepared catalyst was characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and vibrating sample magnetometer techniques. High loading and good dispersion of Fe3O4 nanoparticles on JDC lead to excellent degradation performance for tetracycline (90.2 %, 60 min) and other pollutants (above 80 %), and the reaction rate constant (k) is 3.73 times (0.0384 min−1) than that of pure JDC (0.0103 min−1) in the presence of PMS. Additionally, chemical oxygen demand (COD) removal rate of Fe3O4@JDC/PMS system (64.7 %, 60 min) is best than other systems (JDC system, JDC/PMS system, etc.). The quenching tests and electron paramagnetic resonance (EPR) data further demonstrate that TC degradation is an integrative contribution of both non-radical (1O2) and free radical (O2−, SO4−, and OH) pathways. Furthermore, Fe3O4@JDC also exhibits superior reusability (81.1 % degradation efficiency after five cycles) and magnetic separation ability.
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关键词
Juncus derived carbon,Fe3O4 nanoparticles,Peroxymonosulfate activation,Degradation,Organic pollutants
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