A robust and porous titanium metal-organic framework for gas adsorption, CO2 capture and conversion

A robust and porous titanium metal-organic framework (Ti-MOF; LCU-402) has been hydrothermally synthesized through combining a tetranuclear Ti2Ca2(mu(3)-O)(2)(mu(2)-H2O)(1.3)(H2O)(4)(O2C-)(8) cluster and a tritopic 1,3,5-benzene(tris)benzoic (BTB) ligand. LCU-402 shows remarkable stability and permanent porosity for CO2, CH4, C2H2, C2H4, and C2H6 gas adsorption. Moreover, LCU-402 as a heterogeneous catalyst can smoothly convert CO2 under a simulated flue atmosphere into organic carbonate molecules by cycloaddition reactions of CO2 and epoxides, indicating that LCU-402 might be a promising catalyst candidate in practical applications. We are confident that the identification of a persistent titanium-oxo building unit would accelerate the development of new porous Ti-MOF materials.