Visible-Light Induced Oxidative Annulation of Enamides to 2,4,5-Trisubstituted Oxazole Skeletons
ASIAN JOURNAL OF ORGANIC CHEMISTRY(2023)
摘要
A novel approach to various trisubstituted oxazoles (28 examples, up to 88% yield) has been developed via 9H-thioxanthen-9-one (TX) mediated oxidative annulation of N-acetyl enamide under visible light irradiation in the presence of BF3 center dot Et2O (2.0 equiv) and 40 mol% of PhNO2. This metal-free procedure features high atom and step economy, green and mild conditions and broad substrate scope.
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关键词
Enamides,Hydrogen atom Transfer,Oxazoles,Oxidative annulation,Photocatalysis
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