Nanoporous Mg-doped SiO2 nanoparticles with tunable infrared emissivity toward effective radiative cooling coatings

SiO2 is the hotspot radiative cooling material due to its selective radiation or the Mie resonance effect generated by micro/nanospheres of a specific size. Herein, we demonstrate the modulation of the infrared emissivity of the intrinsic SiO2 at the atmospheric window by doping Mg2+ in nanoporous SiO2 nano-particles via a modified stober method. The effects of the Mg-doping on the crystallinity, morphology, infrared emissivity of the nanoparticles and the radiative cooling properties of the corresponding coatings are investigated. Results show that the Mg-doping at a level of 0.226-2.26 % can induce cristobalite na-nocrystals after sintering at 1000 degrees C, transform the morphology from spheres to irregular nanoporous particles, and improve the infrared emissivity up to 0.96. XPS proves the formation of Mg-O bonds and the change of the binding energy of Si 2p and O 1s, supporting the successful doping of Mg2+ in the lattice of SiO2. All-inorganic Mg-doped SiO2 coatings on FTO substrates are prepared via tape casting, which exhibit rough and porous microstructure and high solar reflectivity up to-86 %, with the thickness of-90 mu m. The Mg-doping improves the radiative cooling capacity of the coatings obviously, and the best temperature reduction of 17.8 degrees C compared with the empty space is achieved, 3-5 degrees C lower than the pure SiO2 coating and 4.5 degrees C lower than the commercial SiO2 coating. Our work offers an effective way to modulate the infrared emission of emitter, enriching the technical measures to improve the overall performance of the sub-ambient radiative cooling devices.(c) 2023 Elsevier B.V. All rights reserved.