Applications and implications of carbon nanotubes for the sequestration of organic and inorganic pollutants from wastewater

The rapid growth in the population, industrial developments, and climate change over the century have contributed to a significant rise in aquatic pollution leading to a scarcity of clean, reliable, and sustainable water sources and supply. Exposure through ingestion, inhalation, and dermal absorption of organic/inorganic compounds such as heavy metals, pharmaceuticals, dyes, and persistent organic pollutants (POPs) discharged from municipalities, hospitals, textile industries, food, and agricultural sectors has caused adverse health outcomes in aquatic and terrestrial organisms. Owing to the high surface area, photocatalytic activity, antimicrobial, antifouling, optical, electronic, and magnetic properties, the application of nanotechnology offers unique opportunities in advanced wastewater management strategies over traditional approaches. Carbon nanomaterials and associated composites such as single-walled carbon nanotubes (SWCNT), multiwalled carbon nanotubes (MWCNT), and carbon nanotubes (CNT) buckypaper membranes have demonstrated efficiency in adsorption, photocatalytic activity, and filtration of contaminants and thus show immense potentiality in wastewater management. This review focuses on the application of CNTs in the sequestration of organic and inorganic contaminants from the aquatic environment. It also sheds light on the aquatic pollutant desorption processes, current safety regulations, and toxic responses associated with CNTs. Critical knowledge gaps involving CNT synthesis, surface modification processes, CNT-environment interactions, and risk assessments are further identified and discussed.