Synthesis of tetrahydrocarbazoles through a radical cation [4+2] cycloaddition reaction of 2-vinylindoles.

Elisa Brambilla, Elisa Moretti,Mirko Magni,Giorgio Abbiati,Valentina Pirovano

Chemical communications (Cambridge, England)（2023）

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摘要

A redox umpolung strategy for the synthesis of complex tetrahydrocarbazoles is reported. The reaction involves a visible light promoted radical cation [4+2] cycloaddition between 2-vinylindoles and conjugated alkenes that proceeds with good yields and diastereoselectivity.

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关键词

tetrahydrocarbazoles,synthesis,cycloaddition reaction,radical cation

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