Synthesis of highly substituted isoquinolines/isoquinolones by ruthenium (ii)-catalyzed reaction of benzyl/alpha-methyl benzyl/benzoyl isocyanates with diaryl alkynes
Chemical communications (Cambridge, England)（2023）
摘要
An efficient and novel method has been developed for the synthesis of highly substituted isoquinolines/isoquinolones by Ru(ii)-catalyzed intermolecular oxidative annulation of benzyl/benzoyl isocyanates with diaryl alkynes in the presence of Cs2CO3 as base and Cu(OTf)(2) as an oxidant at 120 degrees C for 1 h.
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关键词
benzyl/benzoyl isocyanates,isoquinolines/isoquinolones,isoquinolines/isoquinolones,alkynes,benzyl/α-methyl
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