Degradation of Textile Dye by Bimetallic Oxide Activated Peroxymonosulphate Process

The sulphate radical based advanced oxidation processes (AOPs) are highly in demand these days, owing to their numerous advantages. Herein, the Fe-Mn bimetallic oxide particle was used to activate peroxymonosulphate (PMS) for Rhodamine B (RhB) degradation. Three bimetallic catalysts were synthesized via the chemical precipitation method with different concentrations of metals; Fe-Mn (1:1), Fe-Mn (1:2) and Fe-Mn (2:1). The best performance was shown by Fe-Mn (2:1) system at optimized conditions; 96% of RhB was removed at optimized conditions. Scavenging experiments displayed the clear dominance of hydroxyl radical in pH 3, while sulphate radical was present in a large amount at pH 7 and 10. The monometallic Fe and Mn oxides were also synthesized to confirm the synergistic effect that was present in the bimetallic oxide system. The application of optimized condition in real textile wastewater was conducted, which revealed the system works efficiently at high concentrations of PMS and catalyst dosage.