Comparing the reactivity of an oxoiron(IV) cation radical and its oxoiron(V) tautomer towards C-H bonds.

Sandipan Jana,Santanu Pattanayak, Soumadip Das,Munmun Ghosh,Lucia Velasco,Dooshaye Moonshiram,Sayam Sen Gupta

Chemical communications (Cambridge, England)（2023）

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摘要

An oxoiron(IV) cation radical is generated upon two-electron oxidation of an iron(III) complex bearing an electron-rich methoxy substituted bTAML framework and thoroughly characterized multiple spectroscopic techniques and density functional theory (DFT). Reactivity studies demonstrate faster rates for oxidation of strong aliphatic sp C-H bonds than for its corresponding oxoiron(V) valence tautomer.

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关键词

bonds,reactivity,cation

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