Interfacial Engineering of Ni/V 2 O 3 Heterostructure Catalyst for Boosting Hydrogen Oxidation Reaction in Alkaline Electrolytes.

Alkaline fuel cells can permit the adoption of platinum group metal-free (PGM-free) catalysts and cheap bipolar plates, thus further lowering the cost. With the exploration of PGM-free hydrogen oxidation reaction (HOR) catalysts, nickel-based compounds have been considered as the most promising HOR catalysts in alkali. Here we report an interfacial engineering through the formation of nickel-vanadium oxide (Ni/V O ) heterostructures to activate Ni for efficient HOR catalysis in alkali. The strong electron transfer from Ni to V O could modulate the electronic structure of Ni sites. The optimal Ni/V O catalyst exhibits a high intrinsic activity of 0.038 mA cm and outstanding stability. Experimental and theoretical studies reveal that Ni/V O interface as the active sites can enable to optimize the hydrogen and hydroxyl bindings, as well as protect metallic Ni from extensive oxidation, thus achieving the notable activity and durability.