Polynuclear ruthenium clusters containing stibine, stibene, and stibinidene ligands

Mihir L. Bhowmik,Md. Abdullah Al Mamun,Shishir Ghosh,Vladimir N. Nesterov,Michael G. Richmond,Shariff E. Kabir,Herbert W. Roesky

Journal of Organometallic Chemistry（2023）

引用 3|浏览12

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摘要

•Thermolysis of [Ru3(CO)9(SbPh3)(µ-dppm)].•Reactions of [Ru3(CO)10(µ-dppm)] with SbPh3 at different experimental conditions.•Synthesis of triruthenium clusters containing stibene ligand(s) via Sb–Ph bond cleavage.•Synthesis of a hexaruthenium cluster containing stibene and stibinidene ligands.

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关键词

Polynuclear clusters,Antimony ligands,Sb–Ph bond cleavage,X-ray structure, DFT

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