Snow Cover as an Indicator of Dust Pollution in the Area of Exploitation of Rock Materials in the Świętokrzyskie Mountains

Snow cover in environmental monitoring is a valuable resource for information on sources of air pollutants and the level of air pollution. Research in areas of intense industrial pressure without systematic air quality control is of particular importance in this aspect. This is the case in the vicinity of Łagów (an urban–rural municipality) in the eastern part of the Świętokrzyskie Mountains (southern Poland), where rock mining fields have been created over a large area. Limestone, marly limestone and dolomite are mined in this area. The carbonate dust accumulated during the two-week deposition significantly altered the physicochemical and chemical properties of the snow cover. An inductively coupled plasma-mass spectrometer-time-of-flight (ICP-MS-TOF), Dionex 3000 ion chromatograph and Hach HQ2200 water quality meter were used for chemical analyses. The pH, electric conductivity (EC), major ions and selected heavy metals (HM) were determined in water samples obtained after snow melt in two measurement campaigns. The comparative analysis performed showed an increase in pH, EC, Cl, Ca, NO3, SO4 and heavy metals in samples from the two-week old cover (second series) compared to fresh snow (first series). The conducted research indicates a potential hazard for the inhabitants of Łagów due to respirable dusts released into the atmosphere during extraction, processing and transport of rock materials.