Phase behavior and molecular insights on the separation of dimethyl carbonate and methanol azeotrope by extractive distillation using deep eutectic solvents

Jianguang Qi,Yajuan Qu,Mengjin Zhou,Zihao Su,Xiaoying Zhang, Ranran Wei,Ke Xue,Zhaoyou Zhu,Fanqing Meng,Yinglong Wang

Separation and Purification Technology（2023）

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摘要

•The efficient separation of MeOH-DMC binary azeotrope by DESs extractive distillation was studied.•The separation performance of different DESs was compared.•The mechanism of azeotrope separation by DESs was explored at the molecular level.

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关键词

Deep eutectic solvent,Extractive distillation,Microscopic mechanism,Quantum chemistry calculation

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