Preparation of magnetic Fe3O4@PDA/CuS core-shell nanocomposite as a green photocatalyst

To solve the emerging aromatic organic pollutants in aqueous environment, in this study, the efficient recyclable core-shell structured photocatalyst Fe3O4@PDA/CuS was prepared by in situ reduction method. Firstly, Fe3O4 as cores were prepared to provide magnetic recovery. Through the self-polymerization of dopamine (DA), polydopamine (PDA) was coated on Fe3O4 as shells to protect Fe3O4 cores. Then, Cu2+ coordinated with PDA on the surface of Fe3O4@PDA and in situ reduced by Na2S to obtain core-shell structural Fe3O4@PDA/CuS with CuS uniformly growing on the PDA. CuS with a narrow band gap will endow Fe3O4 @PDA/CuS excellent photocatalytic performance for organic dyes degradation. The decomposition rate of methylene blue (MB) reached to 92.1 % within 180 min under visible light irradiation of Fe3O4@PDA/CuS as photocatalyst without any cocatalyst. When pH= 10, the decomposition rate of MB can reach to 92.7 % in 60 min, indicated Fe3O4@PDA/CuS was more suitable for use under alkaline conditions. The capture experiment determined that·OH was the main active substance. This also explained that under alkaline conditions, numerous OH- was conducive to the formation of ·OH, thus accelerated the degradation rate. And the decomposition rate of MB by Fe3O4@PDA/CuS can still reach 83.95 % after reused three times.