A novel Sb-Zn electrode with ingenious discharge mechanism towards high-energy-density and kinetically accelerated liquid metal battery

Hongliang Xie,Peng Chu,Min-an Yang,Zehao Li,Changkun Cai, Yipeng Liu,Jie Wang,Zhaoming Fu,Zhansheng Lu,Zhihong Du,Hailei Zhao

Energy Storage Materials（2023）

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摘要

•A novel dual-active Sb-Zn alloy electrode is elaborately designed.•A unique lithiation mechanism is demonstrated for the first time in LMB field.•The LiZnSb generation enables an elevated discharge voltage platform of 1.1 V.•Zn melts construct in situ rapid electron/lithium percolating networks in cathode.•The Li||Sb-Zn battery attains high energy density and excellent rate capability.

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关键词

Energy storage,Liquid metal battery,Positive electrode,Electrochemical performance,First-principles calculations

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