Solid–liquid transitions in Mn-based ionic liquids [MeIM]2[MnBr4] and [EtIM]2[MnBr4] producing emission spectra with narrow green bands

Seiya Shimono, Masataka Sekine,Yasuhiro Niwa,Hajime Sagayama,Koji Araki,Yoshiaki Hata,Hiroaki Kishimura

Materials Research Bulletin（2023）

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摘要

•Organic–inorganic hybrid materials prepared via conventional solid-state reaction.•Crystal structure and magnetic and optical properties of prepared materials studied.•[MeIM]2[MnBr4] and [EtIM]2[MnBr4] existed in solid state at room temperature.•Luminescence properties caused by phase transitions between solid and liquid states.•Luminescence properties also influenced by the [MeIM]+ and [EtIM]+ cations.

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关键词

Optical materials,Phase transitions,XAFS (EXAFS and XANES),X-ray diffraction,Phosphors

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