Mn-Co bimetallic spinel catalyst towards activation of peroxymonosulfate for deep mineralization of toluene: The key roles of SO4•- and O2•- in the ring-opening and mineralization of toluene

Chemical Engineering Journal(2023)

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摘要
•A MnCo2O4.5 catalyst with excellent activity for PMS activation was fabricated.•MnCo2O4.5/PMS system can efficiently mineralize toluene.•The radicals’ contributions to the conversion and mineralization of toluene were determined.•The toluene degradation routes induced by HO• and SO4•- were detailedly summarized.
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关键词
Toluene conversion,VOCs,PMS,Free radicals,Cobalt manganese spinel catalyst
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