Applying a novel advanced oxidation process of biochar activated periodate for the efficient degradation of bisphenol A: Two nonradical pathways

Chemical Engineering Journal(2023)

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摘要
•Biochar (BC) was effective in periodate (PI) activation for BPA degradation.•BC350 and BC800 exhibited better activation efficiency to PI than other oxidants.•Unique COOIO3 complexes were confirmed as main ROS in BC350 catalyzed processes.•Metastable BC800-PI* complexes led to efficient removal of BPA in BC800/PI systems.
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关键词
Advanced oxidation processes,Periodate,Biochar,Electron-transfer,Density functional theory calculations,Synergistic effect
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