Evaluation of LiNiO2 with minimal cation mixing as a cathode for Li-ion batteries

Chemical Engineering Journal(2023)

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摘要
•LiNiO2 is investigated with a suitable oxygen partial pressure (pO2) at calcination.•The calcination pO2 only affects the surface of LiNiO2 rather than the bulk.•Increasing pO2 decreases the off-stoichiometry of LiNiO2.•The LiNiO2 calcined at the highest pO2 has the 1st capacity of 239.8 mAh g−1 (93.4%).
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关键词
LiNiO2,Oxygen pressure,Synchrotron,Cathode,Lithium-ion battery,Cation mixing
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