Microstructural and electrical properties of AlN–CoCrFeMnNi cermet obtained by hot pressing

Ceramics International(2023)

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摘要
AlN and equimolar ratio of gas atomized CoCrFeMnNi HEA powders were used to prepare AlN–CoCrFeMnNi cermets by ball milling followed by hot pressing sintering at 1240 °C for 2 h. The microstructure characteristics and electrical properties of the cermets were investigated. The sintered cermet bulks were composed of a FCC-structured CoCrFeMnNi solid solution binder phase, AlN phase, and a small amount of Cr7C3 type carbide. No obvious interfacial reaction occurred between AlN and CoCrFeMnNi HEA. The resistivity of AlN–CoCrFeMnNi cermets nonlinearly increased with increasing AlN content and temperature. A conductivity model of AlN–CoCrFeMnNi cermets at room temperature and 600 oC was established based on the generalized effective medium (GEM) equation. Results indicated that AlN–CoCrFeMnNi cermets had a typical percolation threshold phenomenon, which allowed to continuously regulate their resistivity between 102 μΩ cm to 103 μΩ cm as AlN was in the range of 10–50 wt% under room temperature. Therefore, the AlN–CoCrFeMnNi cermets are promising materials for applications in the e-cigarette field.
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关键词
Cermet,High entropy alloy,Sintering,Electrical property
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