Molecular design principles of helical pyramidal chirality self-organized from achiral hexakis(alkyloxy)triphenylene

Dipankar Sahoo,Emad Aqad,Mihai Peterca,Virgil Percec

Giant（2023）

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摘要

•Pyramidal helical, nonhelical, and discotic 3D columnar assemblies.•Supramolecular pyramidal columns of hexakis(alkyloxy)triphenylene.•Crown and disc conformations of triphenylenes in their 3D columnar assemblies.•Decreasing 8/1 pitch to 5/1 and to 2/1 racemizes 3D helical pyramidal columns.•Towards origins of homochirality via simple crown conformations?

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关键词

Chiral helical pyramidal assemblies,Crown and disc constitutional isomers of substituted triphenylenes,Nonhelical pyramidal and discotic columns,Helical and nonhelical pyramidal self-organizations,Molecular design of helical pitch

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