Imidazol-5-one-based donor–acceptor cyclopropanes in reaction with C=S dipolarophiles

Semen E. Nikolaev,Anatolii I. Sokolov,Andrey A. Mikhaylov,Alexander A. Korlyukov,Nadezhda S. Baleeva,Mikhail S. Baranov,Ivan N. Myasnyanko

Chemistry of Heterocyclic Compounds（2023）

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摘要

Interaction of imidazol-5-one-based donor–acceptor cyclopropanes with thiourea and thioacetamide was studied. Previously undescribed spirocyclic 2-amino- and 2-iminotetrahydrothiophenes are formed in the reaction.

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关键词

donor–acceptor cyclopropanes,imidazolones,thioacetamide,thiophenes,thiourea

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