The role of anion in supramolecular aggregation and energetic properties in a series of Cd picolinamide complexes

Marta Počkaj,Romana Cerc Korošec,Zora Popović,Ivana Balić,Muhamed Sućeska,Mario Dobrilović,Tomislav Balić

Polyhedron（2022）

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摘要

The influence of 4 different anions on hydrogen bonding interactions and energetic properties Cd picolinamide complexes have been studied. Bulky, tetrahedral anions inhibit the formation of strong head-to-head amide interaction and azide anion promotes the formation of insensitive energetic coordination polymer.

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关键词

Cadmium(II) complexes,Picolinamide,Anions,Crystal structure,Energetic materials,Coordination polymer

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