Design of Nanostructured Surfaces for Efficient Condensation by Controlling Condensation Modes.

To meet the different needs of various industrial fields, it is of great application value to find a feasible method for controlling the condensation mode on the surface. Inspired by biological surfaces, tuning the surface structure and wettability is considered as a potential way to control the surface condensation behavior. Herein, the coupling effect of the geometric parameters and wettability distribution of the surface on the condensation process has been investigated systematically at the nanoscale. The results illustrate that the condensation mode is primarily determined by the nanopillar wettability when the nanopillars are densely distributed, while the substrate wettability dominates the condensation mode when the nanopillars are sparsely distributed. Besides, the effective contact area fraction is proposed, which more accurately reflects the influence of geometric parameters on the condensation rate of the nanopillar surface at the nanoscale. The condensation rate of the nanopillar surface increases with the increase of the effective contact area fraction. Furthermore, three surface design methods are summarized, which can control the condensation mode of water vapor on the surface into the dropwise condensation mode that generates Cassie-Baxter droplets, and this condensation process is very attractive for many practical applications.