Effects of steam and CO2 on gasification tar composition and evolution of aromatic compounds
Waste Management(2023)
摘要
•Steam promotes tar cracking more than CO2.•CO2 facilitates the cracking of aromatic compounds containing oxygen groups.•Temperature above 800℃ contributes to benzene cracking and reduces H consumption.•Cyclopentadienyl combination can effectively promote naphthalene formation.•H and OH radicals are critical in phenol and benzofuran cracking, respectively.
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关键词
Steam,CO2,Co-gasification,Tar,Aromatic compounds,Rate constant
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