Promoting Photocatalytic Carbon Dioxide Reduction by Tuning the Properties of Cocatalysts.

Suppressing the amount of carbon dioxide in the atmosphere is an essential measure toward addressing global warming. Specifically, the photocatalytic CO reduction reaction (CRR) is an effective strategy because it affords the conversion of CO into useful carbon feedstocks by using sunlight and water. However, the practical application of photocatalyst-promoting CRR (CRR photocatalysts) requires significant improvement of their conversion efficiency. Accordingly, extensive research is being conducted toward improving semiconductor photocatalysts, as well as cocatalysts that are loaded as active sites on the photocatalysts. In this review, we summarize recent research and development trends in the improvement of cocatalysts, which have a significant impact on the catalytic activity and selectivity of photocatalytic CRR. We expect that the advanced knowledge provided on the improvement of cocatalysts for CRR in this review will serve as a general guideline to accelerate the development of highly efficient CRR photocatalysts.