Synthesis of graphdiyne on a copper substrate via a self-coupling reaction.
Physical chemistry chemical physics : PCCP(2022)
摘要
A new strategy is proposed to prepare graphdiyne the self-coupling reaction of hexakis(bromoethynyl)benzene (hBEP) with alkynyl bromide groups. Prominently, the reaction can proceed moderately in 12 h at room temperature. The as-synthesized film displays a porous structure, excellent chemical characteristics, and an admirable catalytic performance for the hydrogen/oxygen evolution reaction (HER/OER).
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