Insights into Self-Assembly of Nonplanar Molecules with Aggregation-Induced Emission Characteristics

Utilizing nonplanar conjugated molecules as building blocks facilitates the development of self-assembly but is fundamentally challenging. To study the self-assembly behavior, we herein demonstrate the self-assembly process of a nonplanar conjugated molecule with aggregation-induced emission (ALE) feature from an isolated molecule to an irregular cluster to a well-defined vesicle driven by amphiphiles. The superhigh aggregation-sensitive emission affords more precise and detailed information about the self-assembly process than traditional dyes. Meanwhile, the arrangements of the ALE-active molecule change from disordered to well-organized forms by reducing the twisted configuration during the transformation process, and the strong hydrophobicity of amphiphiles is crucial for such configuration and morphology transformations. Owing to the thermophilic bacteria-mimetic membranes, the obtained vesicles exhibit a property of superhigh thermal stability. They also display promising light-harvesting applications. This work not only deciphers the self-assembly of ALE molecules but also provides a strategy for nonplanar molecules to build well-organized self-assemblies.