HALOGEN-BONDED SUPRAMOLECULAR ARCHITECTURES INVOLVING 2,7-DIPYRIDYLFLUORENE AND 1,3,5-TRIFLUORO-2,4,6-TRIIODOBENZENE TECTONS - A SPECTACULAR EVOLUTION FROM CATEMERS TO 2D HALOGEN BOND ORGANIC FRAMEWORKS (XBOF)

Lidia Cata,Ioana Georgeta Grosu,Maria Miclaus,Niculina Daniela Hadade,Ion Grosu,Anamaria Terec

STUDIA UNIVERSITATIS BABES-BOLYAI CHEMIA（2022）

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摘要

A spectacular 2D Halogen Bond Organic Framework (XBOF) was prepared by the mechanochemical solvent-drop grinding method (SCD) starting from 2,7-dipyridylfluorene and 1,3,5-trifluoro-2,4,6-triiodobenzene tectons. The formation of the supramolecular assembly was proved by powder X-ray diffraction measurements and the structural details were collected from the single crystal X-ray diffraction investigations.

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关键词

N???I and I???F halogen bonds, XBOFs, dipyridylfluorene, 1, 3, 5-trifluoro-2, 4, 6-triiodobenzene, single crystal X-ray diffraction structure

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