MACROCYCLIC COMPOUNDS FORMED IN THE REACTION OF 3,7-BIS(ORTHO-, META- OR PARA-FORMYLPHENYL)PHENOTHIAZINES WITH META-BIS(AMINOMETHYL)BENZENE: EXPERIMENTAL AND THEORETICAL INVESTIGATIONS

Ioan Stroia, Monica Irina Nan, Elena Bogdan,Anamaria Terec,Niculina D. Hadade,Ion Grosu

REVUE ROUMAINE DE CHIMIE（2022）

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摘要

The competition among oligomeric macrocycles and mechanically interlocked structures ([2]catenanes) in imine formation cyclization reactions of isomeric 3,7-bis(ortho-, meta- or para- formylphenyl)phenothiazines with meta-bis(aminomethyl)benzene is experimentally revealed and investigated by detailed DFT calculations.

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