Design, Synthesis, and Evaluation of Extended C4-Symmetric Dirhodium Tetracarboxylate Catalysts

Zachary J. Garlets,Yannick T. Boni,Jack C. Sharland, Randall P. Kirby,Jiantao Fu,John Bacsa,Huw M. L. Davies

ACS CATALYSIS（2022）

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摘要

The synthesis and evaluation of six C-4-symmetric bowl-shaped dirhodium tetracarboxylate catalysts are described. These elaborate high-symmetry catalysts are readily generated by means of the self-assembly of four C-1-symmetric ligands around the dirhodium core. These catalysts are capable of highly site-selective, diastereoselective, and enantioselective C-H functionalization reactions by means of donor/acceptor carbene-induced C-H insertions.

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关键词

C-H functionalization, donor-acceptor dirhodium carbene, aryldiazoacetate

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