A review of catalytic hydrogenation of carbon dioxide: From waste to hydrocarbons.

With the rapid development of industrial society and humankind's prosperity, the growing demands of global energy, mainly based on the combustion of hydrocarbon fossil fuels, has become one of the most severe challenges all over the world. It is estimated that fossil fuel consumption continues to grow with an annual increase rate of 1.3%, which has seriously affected the natural environment through the emission of greenhouse gases, most notably carbon dioxide (CO). Given these recognized environmental concerns, it is imperative to develop clean technologies for converting captured CO to high-valued chemicals, one of which is value-added hydrocarbons. In this article, environmental effects due to CO emission are discussed and various routes for CO hydrogenation to hydrocarbons including light olefins, fuel oils (gasoline and jet fuel), and aromatics are comprehensively elaborated. Our emphasis is on catalyst development. In addition, we present an outlook that summarizes the research challenges and opportunities associated with the hydrogenation of CO to hydrocarbon products.