Stereoselective electrochemical carboxylation of α,β-unsaturated sulfones
Chinese Chemical Letters(2022)
摘要
As an attractive C1 synthon, carbon dioxide (CO2) has been extensively used in organic synthesis to produce carboxylic acids. In this research, stereoselective electrochemical carboxylation of α,β-unsaturated sulfones has been developed under transition-metal-free conditions. All the cinnamic acids and the derivatives are obtained selectively in the E-configuration. Besides, arylpropiolates also can be produced from alkynyl sulfones.
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关键词
stereoselective electrochemical carboxylation
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