A C3-symmetric triple oxa[6]helicene with circularly polarized luminescence featuring parallel transition dipole moments.

We present the synthesis and characterization of the first triple oxa[6]helicene with C3 symmetry. In contrast to the reported D3-symmetric triple oxa[7]helicene, the C3-symmetric analogue holds parallel electric and magnetic transition dipole moments and thus enhanced luminescence dissymmetry, shedding light on the critical role of molecular symmetry on chiroptical response.