Regioselective synthesis of -hydroxy sulfides using aryl halides

Najmeh Nowrouzi,Mohammad Abbasi,Elham Shaikhi Shahidzadeh

Applied Organometallic Chemistry（2023）

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摘要

Cyanodithioformate salt as an odorless and simply operational source of sulfur was reacted with aryl halides in the presence of copper iodide, affording diaryl disulfide, which reacted with styrenes/alpha-methylstyrene in second step to form beta-Hydroxy sulfides with high regioselectivity in good to excellent yields.

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关键词

aryl halides,cyanodithioformate,diaryl disulfide,styrene,beta-hydroxy sulfides

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