Immobilization of Ag and Pd over a novel amide based covalent organic framework (COF-BASU2) as a heterogeneous reusable catalyst to reduce nitroarenes

Inorganica Chimica Acta(2022)

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摘要
•A new strategy was designed to synthesize a new amide-based COF through the reaction between 1,4‑diaminobenzene and trimesic acid (BTC).•The surface of synthesized COF (COF-BASU2) is decorated via silver (Ag) and palladium (Pd) ions to synthesize Ag/COF-BASU2 and Pd/COF-BASU2.•Ag/COF-BASU2 was used as a potential catalyst for the reduction of nitrobenzene derivatives in the presence of NaBH4.•Pd/COF-BASU2 was used as a potential catalyst for the reduction of nitrobenzene derivatives in the presence of H2.•According to the obtained results, using Ag/COF-BASU2 offers the highest yields in the shortest reaction time.
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关键词
Catalysis,Heterogeneous catalyst,Covalent organic framework,Nitroarenes reduction,Palladium,Silver
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