NMR and theoretical analyses of electronic effects in N-BH3 adducts of (1,3,5-dithiazin-2-yl)silanes and stannanes. Intramolecular interactions of chemically identical S···S atoms

Angelina Flores-Parra,Pedro Montes-Tolentino,German Rodriguez-Lopez,Iris Ramos-Garcia,Tayde Osvaldo Villasenor-Granados

Journal of Molecular Structure（2022）

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摘要

•N-BH3 adducts of (5-methyl-1,3,5-dithiazin-2-yl)silanes and stannanes.•Long-distance electronic effects detected by NMR spectroscopy.•Theoretical analysis of weak intramolecular interactions.•Through-the-space S···S, S···Si and S···Sn intramolecular interactions.•Intramolecular interactions in chemically identical sulphur-sulphur atoms.

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关键词

(5-Methyl-1,3,5-dithiazin-2-yl)silanes/stannanes N-BH3 adducts,NMR long-distance electronic effects,Weak intramolecular atomic interactions,Through-the-space sulphur intramolecular interactions,Chemically identical sulphur-sulphur interactions

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