Coordinative diversity in mononuclear CuI and CuII complexes of O,N,S-ambidentate camphoriminoquinone ligands
Inorganica Chimica Acta(2022)
摘要
•Camphoriminoquinones can act as ligands towards CuI and CuII.•Copper prefers O,N chelation with long Cu···O bonds in both cases.•An additional thioether function leads to Cu-S coordination.•CuII complexes exhibit variable structural distortion.
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关键词
Ambidentate ligands,Camphorquinone,Chelate complexes,Copper coordination compounds,Molecular structure
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