Coordinative diversity in mononuclear CuI and CuII complexes of O,N,S-ambidentate camphoriminoquinone ligands

Inorganica Chimica Acta(2022)

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摘要
•Camphoriminoquinones can act as ligands towards CuI and CuII.•Copper prefers O,N chelation with long Cu···O bonds in both cases.•An additional thioether function leads to Cu-S coordination.•CuII complexes exhibit variable structural distortion.
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关键词
Ambidentate ligands,Camphorquinone,Chelate complexes,Copper coordination compounds,Molecular structure
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