Paleoenvironment of Mesoproterozoic Gaoyuzhuang and Wumishan Formations, North China: New Insights from Geochemistry and Carbon and Oxygen Isotopes of Dolostones

The Mesoproterozoic Gaoyuzhuang and Wumishan Formations are major geothermal reservoirs in the Hebei Province, North China. Compared to the exploration of geothermal resources and heat-controlling structures, carbon and oxygen isotopic records of the two formations are limited. Here, we present integrated field, petrological, geochemical, carbon, and oxygen isotopic data of carbonate rocks from the Gaoyuzhuang and Wumishan Formations. The Wumishan Formation is characterized by higher CaO and MgO contents and lower SiO2 contents than the Gaoyuzhuang Formation, indicating that the source of the Wumishan Formation likely contains less terrigenous clastic materials. The two formations have low total rare earth element contents, similar to marine carbonate rocks. They show different Eu and Ce anomalies, Al/(Al + Fe + Mn) and Fe/Ti ratios, and (Co + Ni + Cu) contents. They generally show similar carbon isotopic compositions, whereas the carbonate rocks of the middle-upper Gaoyuzhuang Formation show lower delta O-18 values than the samples from the Wumishan and lower Gaoyuzhuang Formations. These data suggest that the two formations have experienced different transgressive-regressive cycles and that their sedimentary environments varied and were unstable in different sedimentary periods. The middle-upper Gaoyuzhuang Formation was likely affected by hydrothermal fluids, whereas the Wumishan Formation is composed of normal seawater deposits. Integrated evidence reveals that both of the Mesoproterozoic Gaoyuzhuang and Wumishan Formations were deposited in rift environments caused by the breakup of the Columbia/Nuna supercontinent.