Fe-Al bimetallic oxides functionalized-biochar via ball milling for enhanced adsorption of tetracycline in water.
SSRN Electronic Journal(2022)
摘要
The clusters formed by modified materials on its surface makes the application of functionalized biochars in adsorption face a great challenge. Here, a facile ball milling technology was innovatively proposed to tailor Fe-Al oxides-laden bagasse biochar to fabricate a novel adsorbent (BMFA-BC). Benefited from the increased exposure of Fe-Al oxides and, more importantly, enhanced functional groups by ball milling, the adsorption capacity of BMFA-BC for aqueous tetracycline reached up to 116.6 mg g at 298 K. And the adsorption performance was temperature-dependent. Characterization analysis, batch sorption (thermodynamics, kinetics, isotherms, chemical factors) as well as data modeling illustrated that this superior adsorption ability could be attributed to π-π conjugation, H-bonding, complexation as well as pore filling. BMFA-BC displayed good adsorption capacity in multiple aqueous environments. The excellent regeneration ability, magnetic susceptibility ensured its viability for sustainable pollutants removal. These superiorities revealed that BMFA-BC was a suitable sorbent for antibiotics elimination.
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关键词
Bagasse biochar,Ball milling,Bimetallic oxides,Sorption,Tetracycline
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