Manganese N,N,N-Pincer Complex-catalyzed Epoxidation of Unactivated Aliphatic Olefins

Dennis Verspeek, Sebastian Ahrens,Anke Spannenberg,Xiaodong Wen,Yong Yang,Yongwang Li,Kathrin Junge,Matthias Beller

Catalysis Science & Technology（2022）

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摘要

A practical in situ generated manganese(II) catalyst system with the commercially available bis(2-picolyl) amine ligand enables epoxidation of terminal aliphatic olefins in good yields with tert-butyl hydroperoxide as oxidant. Crystallization...

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