Effects of Nb-modified CeVO4 to form surface Ce-O-Nb bonds on improving low-temperature NH3-SCR deNOx activity and resistance to SO2 & H2O

Fuel(2023)

引用 23|浏览8
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摘要
•Synthesis of novel ternary CeVO4 modified with different Nb contents catalysts.•>90 % NO conversion in the range of 210–420 °C with 5 %vol·H2O over CeNbVO-2.•Enhancing the surface acidity on CeNbVO-2 by adding proper amount of Nb.•Increase in active oxygen species due to formation of CeVO4 with Nbn+–O2−-Cen+ bonds.•Good activity assigned to the synergistic effect between acidity and redox property.
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关键词
Selective catalytic reduction with NH3,NOx removal,Nb-modified CeVO4 phase,Surface Nbn+–O2--Cen+ bonds,Role of acidity
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