A cobalt(II) porphyrin with a tethered imidazole for efficient oxygen reduction and evolution electrocatalysis

Xialiang Li,Ping Li,Jindou Yang,Lisi Xie,Ni Wang,Haitao Lei,Chaochao Zhang,Wei Zhang,Yong-Min Lee,Weiqiang Zhang,Shunichi Fukuzumi,Wonwoo Nam,Rui Cao

Journal of Energy Chemistry（2023）

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摘要

A Co porphyrin with a tethered imidazole for Co axial binding is synthesized and outperforms its imidazole-free analogue for electrocatalytic oxygen reduction and evolution reactions in alkaline aqueous higher resolution.

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关键词

Molecular electrocatalysis,Cobalt porphyrin,Axial ligand effect,Oxygen reduction reaction,Oxygen evolution reaction

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