On the energetics of binding and hydride exchange in the RuH₂(H₂)₂[P(C₅H₉)₃)]₂ complex as revealed by inelastic neutron scattering and DFT studies

New Journal of Chemistry（2022）

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摘要

Low temperature quantum rotation of dihydrogen in RuH2(H2)2[P(C5H9)3)]2 switched to a facile hydride exchange above 150 K.

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On the energetics of binding and hydride exchange in the RuH2(H2)2[P(C5H9)3)]2 complex as revealed by inelastic neutron scattering and DFT studies