Enantioselective synthesis of 5- to 16-membered N-heterocycles via a Pd-catalyzed cascade
Chem Catalysis(2022)
摘要
In this issue of Chem Catalysis, Huang and co-workers demonstrate the synthetic utility of an enantioselective palladium-catalyzed cascade reaction that is underpinned by a s- bond C-N metathesis/ isomerization/Csp3-Pd migratory insertion sequence. The capacity of thismethodology to reliably and stereoselectively construct saturated 5-membered to macrocyclic N-heterocycles underscores the broad scope and impressive flexibility of this approach.
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关键词
enantioselective synthesis,n-heterocycles,pd-catalyzed
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