Chemoenzymatic catalysis of tert-butyl 6-cyano-(3R,5R)-dihydroxyhexanoate by aldo-keto reductase coupled with composite Fe3O4 nanozyme scaffold

Shuai Qiu,Shen-Yuan Xu,Ya-Jun Wang,Yu-Guo Zheng

Chemical Engineering Science（2022）

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摘要

•A novel Fe3O4 nanozyme catalyst scaffold Fe3O4@HMWCNTs has been designed and synthesized.•Fe3O4@HMWCNTs can transfer hydrogenation of NADP+ to NADPH efficiently and repeatedly.•Fe3O4@HMWCNTs and natural enzyme are compatible.•Various chiral alcohols can be synthesized via Fe3O4@HMWCNTs coupled with KmAKRM7.

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关键词

Chemoenzymatic catalysis,Nanozyme,Aldo-keto reductase,Carbon nanotubes,Cofactor regeneration,Chiral alcohol

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