Activity coefficients at infinite dilution via a perturbation method of NRHB model

A. Baldanza,G. Scherillo,G. Mensitieri,C. Panayiotou

Chemical Engineering Science（2022）

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摘要

•Expressions for activity coefficients at infinite dilution of mixtures of low molecular weight fluids.•Analytical expressions are obtained via perturbation of Non-Random Hydrogen Bonding EoS model.•The approach accounts for specific intermolecular and intramolecular interactions.

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关键词

Phase equilibria,Hydrogen-bonding,Solvation,Non-random distribution,Equation-of-state

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