Click chemistry tailored benzimidazole functionalized triazole block-co-polymer for emergence of exotic chimaeric nano-crystalsomes

•Click chemistry approach has been utilized to achieve molecular level crystallinity.•Self-assembly of polymers with morphological transitions giving rise to exotic nanostructures.•Chimaeric crystalsomes (DPCM) is generated as a result of translational symmetry breaking in the crystallization process, lamellar folding and side chain orientation.•Owing to the remarkable anti-inflammatory, antibacterial, and analgesic activity, these chimaeric crystalsomes (DPCM) can efficiently accelerate wound healing.