Surface Coating with Naphthalene Trisulfonate/Hafnium(IV) Complexes: Versatility and Post-Functionalization.
Langmuir : the ACS journal of surfaces and colloids(2022)
摘要
Naphthalene trisulfonate is found to have versatile surface coating capability when combined with hafnium(IV) ions, thereby forming complexes. Solid substrates such as titanium/titanium dioxide, glass, and nylon immersed in a solution of naphthalene trisulfonate and Hf produces naphthalene trisulfonate/Hf complex coating. The coating is not produced when the Hf ions are absent or when naphthalene monosulfonate replaces naphthalene trisulfonate; this indicates the significance of Hf ions and multiple sulfonates in this coating system. The versatile surface coating property of naphthalene trisulfonate/Hf complexes is attributed to the coexistence of hydrophobic aromatic and hydrophilic side groups in naphthalene trisulfonate. Additionally, Hf ion-mediated cross-linking reactions between naphthalene trisulfonate molecules induce molecular assembly, facilitating versatile surface coating. Post-functionalization of the coating is accomplished through additional Hf-mediated coordinate bond formation; alginate and λ-carrageenan are successfully grafted onto the coating for nonbiofouling applications.
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