Construction of a photoluminescent Zn(II)-based 2D MOF via in situ cis-trans isomerization of cis,cis-muconate ligand

Taposi Chatterjee, Ersad Hossain,Samim Khan,Sourav Roy,Saikh Mohammad Wabaidur,Md Ataul Islam,Seikh Mafiz Alam,Mohammad Hedayetullah Mir

Journal of Molecular Structure（2023）

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摘要

•X-ray crystallographic analysis of a new Zn(II)-based metal-organic framework (MOF).•Structural analysis reveals the formation of 2D square-grid framework with (4,4) net topology.•In situ cis-trans isomerization of cis,cis- muconate ligand in visible light.•The compound reveals photoluminescence property as examined by fluorescence spectroscopy.

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关键词

Hirshfeld analysis,In situ isomerization,Metal-organic framework,Photoluminescence,Zn(II)

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